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Molecular Relaxation in Liquids, by Biman Bagchi
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This book brings together many different relaxation phenomena in liquids under a common umbrella and provides a unified view of apparently diverse phenomena. It aligns recent experimental results obtained with modern techniques with recent theoretical developments. Such close interaction between experiment and theory in this area goes back to the works of Einstein, Smoluchowski, Kramers' and de Gennes. Development of ultrafast laser spectroscopy recently allowed study of various relaxation processes directly in the time domain, with time scales going down to picosecond (ps) and femtosecond (fs) time scales. This was a remarkable advance because many of the fundamental chemical processes occur precisely in this range and was inaccessible before the 1980s. Since then, an enormous wealth of information has been generated by many groups around the world, who have discovered many interesting phenomena that has fueled further growth in this field.
As emphasized throughout the book, the seemingly different phenomena studied in this area are often closely related at a fundamental level. Biman Bagchi explains why relatively small although fairly sophisticated theoretical tools have been successful in explaining a wealth of experimental data at a semi-phenomenological level.
- Sales Rank: #3085151 in Books
- Published on: 2012-04-17
- Original language: English
- Number of items: 1
- Dimensions: 6.40" h x .90" w x 9.40" l, 1.30 pounds
- Binding: Hardcover
- 336 pages
Review
"The past 30 years has seen great progress in the microscopic understanding of dynamical processes in liquids and solutions. Ultrafast spectroscopy, modern statistical mechanics, and numerical computer simulation have been developed with highly productive synergies and feedbacks. Biman Bagchi has been at the center of the interplay of theory, simulation, and experiment during this whole period, making it highly appropriate that he has written a book aimed at placing the theoretical techniques and results in the context of the key experimental results." -- Graham R. Fleming, Vice Chancellor for Research, University of California, Berkeley
About the Author
Biman Bagchi is Professor at the Indian Institute of Science in Bangalore, India.
Most helpful customer reviews
0 of 0 people found the following review helpful.
Bridging theory and experiments very nicely. Highly recommended.
By Rajesh K. Murarka
This book deals with various relaxation processes in liquid solutions with a strong emphasis on the inter-connection between experiments and theory. Two relaxation processes, viz., the solvation dynamics and the barrier crossing dynamics, have been discussed lucidly and with the desired expertise. The role of intermolecular correlations in guiding the relaxation processes and their reflections on experimental measurements have been elaborated. The strong relationship between theory and experiments has been maintained all through this book, and this is one of the strongest points.
In a more detail, the first four chapters (a total page ~50) lucidly present the basic concepts of various relaxation processes and their phenomenological descriptions, and a possible link that could connect the measurements to a proper theoretical quantity which can be calculated or computed. Here a physical picture has been developed which serves beautifully to those not only who are already in this field but to those also who are planning to join in. The other chapters deal with more specific examples of other relaxation processes in various media. This can be a useful reference book (with a total text-page of ~300) for relaxation phenomena in general and liquids in particular. This also complements the book by Zwanzig (Non-equilibrium Statistical Mechanics, OUP, 2001). Such a book is a much-needed one as not much in the text-book level (even if advanced) was available even-though research progressed immensely in this area through a symbiosis between theory and experiments for the last 30 years or so. It's pleasing that such a text-book level discussion has finally emerged from the desk of a scientist who is one of the global-leaders in this arena and a keen observer. A second edition with suitable illustrations is thus a natural demand from such an expert author.
0 of 0 people found the following review helpful.
Comprehensive and educational book
By shinji
I really like this book.
This book is comprehensive and educational; it covers many important subjects in physical chemistry and chemical physics.
In addition, Bagchi is strongly conscious of the relationship between theories and experiments in this book. This is a very important and required view for both theoretical and experimental students and young researchers.
Furthermore, we can see his distinctions in many chapters; he unrolled his theories by starting from microscopic considerations as well as phenomenological approaches.
I highly recommend this book as a text for an advanced graduate course or at least as a supplement for the advanced course.
0 of 0 people found the following review helpful.
Great resource for both research and teaching community
By Goud
This book is a great resource for both research and teaching community. It describes principles of relaxation phenomena in molecular liquids in much detailed fashion, which greatly helps students especially from physical chemistry and chemical physics community. Basic principles associated with molecular relaxation (in solvents) such as dielectric relaxation, chemical kinetics, electron transfer, diffusion phenomena etc. have been discussed in depth. Most of the equations are derived in detailed fashion using fundamental principles that greatly aid students understanding. One highly beneficial fact of this book is it beautifully relates theoretical framework of molecular liquids with contemporary experiments in a simple and straightforward fashion. For example, there is a dedicated chapter explaining theory behind fluorescence resonance energy transfer (FRET) and directly relating it to FRET experiments. I envisage this to be a required textbook for course work involving physical chemistry and chemical physics along with molecular simulations.
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